New Porous Crystals of Extended Metal-Catecholates Guolong Xing, Jingjuan Liu, Yi Zhou, Shuai Fu, Jia-Jia Zheng, Xi Su, Xingfa Gao, Osamu Terasaki, Mischa Bonn, Hai I Wang, Long Chen Conjugated Nonplanar Copper-Catecholate Conductive Metal–Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
Metal-Catecholate Frameworks as Solid Basic Catalysts Metal catecholate frameworks, based on 2,3,6,7,10,11-hexahydroxytriphenylene and bivalent metal ions (Ni2+, Cu2+, Zn2+, Mg2+, Ca2+, Sr2+ and Ba2+) were synthesized, characterized with powder X-ray diffraction and N2 physisorption, and evaluated as catalysts in Knoevenagel condensation and Michael addition reactions The large number of catecholate oxygen atoms in these materials resulted in a
New Porous Crystals of Extended Metal-Catecholates - 百度学术 M Hmadeh，Z Lu，Z Liu，F Gándara，H Furukawa，S Wan ，V Augustyn，R Chang，L Liao，F Zhou 展开 摘要： New porous crystals of extended metal catecholates 展开 关键词： metal catecholates high-resolution transmission electron microscopy
Angewandte Chemie International Edition - Wiley Online Library The π-d conjugated framework exhibits typical semiconducting behavior with a high electrical conductivity of ca 1 0 S m −1 at room temperature Benefiting from the good electrical conductivity and the excellent redox reversibility of both ligand and copper centers, Cu-DBC electrode features superior capacitor performances with gravimetric
New Porous Crystals of Extended Metal-Catecholates - OSTI. GOV These new crystalline materials, termed metal-catecholates (M-CATs), were characterized by X-ray diffraction techniques (single crystal for Co-CAT-1, and powder for Ni-CAT-1) and high-resolution transmission electron microscopy (HR-TEM) studies (for Ni-CAT-1)
Mohamad Hmadeh - Google Scholar M Hmadeh, Z Lu, Z Liu, F Gándara, H Furukawa, S Wan, V Augustyn, Chemistry of Materials 24 (18), 3511-3513, 2012 838: 2012: Crystal growth of ZIF-8, ZIF-67, and their mixed-metal derivatives 2012: Highly Efficient Ambient Temperature CO 2 Photomethanation Catalyzed by Nanostructured RuO 2 on Silicon Photonic Crystal Support
New Porous Crystals of Extended Metal-Catecholates These new crystalline materials, termed metal-catecholates (M-CATs), were characterized by X-ray diffraction techniques (single crystal for Co-CAT-1, and powder for Ni-CAT-1) and high-resolution transmission electron microscopy (HR-TEM) studies (for Ni-CAT-1)
Large-pore apertures in a series of metal-organic frameworks We report a strategy to expand the pore aperture of metal-organic frameworks (MOFs) into a previously unattained size regime (>32 angstroms) Specifically, the systematic expansion of a well-known MOF structure, MOF-74, from its original link of one phenylene ring (I) to two, three, four, five, s …