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催化反应中的动力学同位素效应(KIE) - mumuxili. com 1 KIE概念: 在《大学化学词典》中对同位素效应的定义如下:”同一元素的同位素具有相同的电子构型,因而具有相似的化学性质。 但同一元素的不同的同位素具有不同的质量,它们虽然能发生相同的化学反应,但平衡常数有所不同,反应速率也有所不同。
动力学同位素效应有关(有机化学常见效应 Day 2) - 知乎 此处需要强调,除非对两个反应模式相似的反应进行对比,否则KIE不能反推反应吸放热特点 成键断键程度 过渡态,原因就在于KIE作为实验上的反应速率之比,显然受到复杂的多种因素共同影响,有的时候,我们甚至需要考虑引入C-D键带来的微弱“化学性质
10. 2. 0 (latest) | Apache KIE (incubating) Apache KIE (incubating) is released as source code tarball with different binaries for convenience This page aims to consolidate all the artifacts available
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