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- Supramolecular rosette intermediated homochiral double helix
Here, we report that a type of bisnaphthalene bisurea molecule could assemble into chirality-controlled nanoscale double-helices by a supramolecular rosette-intermediated hierarchical
- Supramolecular Chirality in Dynamic Coordination Chemistry
This review provides recent examples of chirality induction and describes the dynamic conversion systems produced by chiral metal complexes including labile metal centers, most of which respond to external stimuli by exhibiting sophisticated conversion phenomena 1 Introduction
- Structure and Dynamics of Supramolecular Polymers: Wait and See
It is proposed that the polymer of the chiral monomer needs time to arrive at its maximal preference in helical bias These results indicate that the order and tight packing increase over time, while the dynamics of this supramolecular polymer decrease over time, an effect that is typically overlooked but unveiled by the isotopic chirality
- Emergent chiroptical properties in supramolecular and . . .
In supramolecular systems, induced circular dichroism (ICD) originates through the off-resonance coupling of transition dipoles in chiral inclusion complexes, while exciton coupled circular dichroism (ECD) originates through the on-resonance exciton coupling of transition dipoles in chiral assemblies resulting in the formation of a bisignated
- Into the Dynamics of a Supramolecular Polymer at Submolecular . . .
Here we show atomistic, coarse-grained modelling combined with advanced simulation approaches to characterize the molecular mechanisms and relative kinetics of monomer exchange in structural
- Three‐Level Chirality Transfer and Amplification in Liquid . . .
Chiral liquid crystal supramolecular assembly provides an ideal strategy for constructing excellent circularly polarized luminescence (CPL) materials However, the chirality transfer in chiral liquid crystals normally occurs at two levels from the configurational chirality to the supramolecular phase chirality
- Chirality Evolution of Supramolecular Helices by Electron . . .
Herein, the chirality evolution of supramolecular helices based on l -phenylalanine derivative (LPF) and naphthylamide derivate (NDIAPY) is achieved by the strategy of electron transfer (ET) assisted secondary nucleation
- Chiral self-assembly of peptides: Toward the design of . . .
Peptides, as a class of small biomolecules, can self-assemble into various chiral supramolecular polymers with unprecedented levels of diversity and complexity, which have practical ramifications in various fields from catalysis to sensing, optics, and biomedicine
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